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Sodium Acetate MSDS; Handling & Hazard

 


1. Product Identification

Synonyms: Sodium acetate trihydrate; Acetic acid, sodium salt trihydrate
CAS No.: 127-09-3 (Anhydrous); 6131-90-4 (Trihydrate)
Molecular Weight: 136.08
Chemical Formula: CH3COONa 3H2O


2. Composition/Information on Ingredients

  Ingredient                                	CAS No         	Percent        	Hazardous                                  
  ---------------------------------------   		------------  		 ------------   	---------   
  Sodium Acetate                            	127-09-3         	99 - 100%       	Yes                                                                    

3. Hazards Identification

Emergency Overview
--------------------------
CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
-----------------------------------------------------------------------------------------------------------
Health Rating: 1 - Slight
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code: Orange (General Storage)
-----------------------------------------------------------------------------------------------------------
Potential Health Effects
----------------------------------
Inhalation: Sodium Acetate may cause irritation to the respiratory tract. Symptoms may include coughing, sore throat, labored breathing, and chest pain.
Ingestion: Sodium Acetate large doses may produce abdominal pain, nausea, and vomiting.
Skin Contact: Sodium Acetate may cause irritation with redness and pain.
Eye Contact: Sodium Acetate contact may cause irritation, redness, and pain.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found for Sodium acetate.


4. First Aid Measures

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts of Sodium acetate were swallowed, get medical advice.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.


5. Fire Fighting Measures

Fire: Autoignition temperature: 611C (1132F). As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source. Listed fire data is for the Anhydrous Sodium acetatel.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.


6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill of Sodium acetate. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. Small amounts of residue may be flushed to sewer with plenty of water.


7. Handling and Storage

Keep Sodium acetate in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from any source of heat or ignition. Containers of Sodium acetate may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.


8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established for Sodium acetate.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.


9. Physical and Chemical Properties

Appearance: Colorless crystals.
Odor: Slight acetic acid odor.
Solubility: 76 gm/100mls water @ 0C
Density: 1.45
pH: 8.9
% Volatiles by volume @ 21C (70F): 0
Boiling Point: Not applicable.
Melting Point: Loses water @ 120C (248F); decomposes @ 324C (615.2F)
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): No information found.
Evaporation Rate (BuAc=1): No information found.


10. Stability and Reactivity

Stability: Sodium Acetate is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Sodium Acetate emits fumes of acetic acid upon heating and on contact with strong acids.
Hazardous Polymerization: Will not occur.
Incompatibilities: Nitric acid, fluoride, potassium nitrate, strong oxidizers and diketene.
Conditions to Avoid: Incompatibles.


11. Toxicological Information

Hydrate: Investigated as a mutagen. Anhydrous: Oral rat LD50: 3530 mg/kg; inhalation rat LC50: > 30 gm/m3; skin rabbit LD50: > 10 mg/kg; Irritation Data, standard Draize: Skin rabbit 500 mg/24H, mild; standard Draize, Eye rabbit 10 mg, mild. Investigated as a mutagen.


12. Ecological Information

Environmental Fate: No information found on Sodium acetate.
Environmental Toxicity: No information found.


13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of Sodium acetate and unused contents in accordance with federal, state and local requirements.


14. Transport Information

Not regulated.


15. Regulatory Information

Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Pure / Solid) 
Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 1 Reactivity: 0
Label Hazard Warning:
CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Avoid breathing dust.
Use with adequate ventilation.
Wash thoroughly after handling.
Keep container closed.
Label First Aid: If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Disclaimer:
************************************************************************************************
Our company provides this MSDS information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This SODIUM ACETATE MSDS document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. ************************************************************************************************

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For more information contact manufacturer at:
MUBY CHEMICALS
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TEL: (OFFICE) 91-22-23770100, 23774610, 23726950, 23723564. FAX: 91-22-23728264.

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Last updated: October 08, 2009

 

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